I've been using a standard template profile for years.
I had to reinstall my machine, and for some reason... the copy/move will not occur to the network share using a dvrms setting profile..
I can open the path from my windows 7, no problem.(start..run....\\Home-Server\TV\Whatever)
Start Process: 4/2/2012 : 6:47 PM
InputFile=C:\Users\Public\Recorded TV\How I Met Your Mother_WWOR_2012_04_01_19_31_59.wtv
Processing actions, this may take some time!!
Current Affinity: 63 System Mask: 63
Testing "Processed Files"
"Test" is a match.
Run Profile = Test
ProcessId = 3248
DvrmsToolbox Version: 188.8.131.52
FWThrottle: C:\Users\Public\Recorded TV\How I Met Your Mother_WWOR_2012_04_01_19_31_59.wtv
WaitTime: 5 PollTime
Waiting to process file
Duration = 00:00:01.0139935
Waiting for available worker: 4/2/2012 6:48 PM
Worker allocated: 4/2/2012 6:48 PM
Move the file in Context["InputFile"] to \\Home-Server\TV\Test
\\Home-Server\TV\Test does not exist
Action did not complete successfully
Total Duration = 00:00:01.0451933
I've reinstalled dvrms and broken down the more complex profile to what you see above.